Problems On Retrosynthesis

Problems On Retrosynthesis-26
And so looking at the structure, all right, we know that there's a hydrogen attached to our alpha carbon like that.

And so looking at the structure, all right, we know that there's a hydrogen attached to our alpha carbon like that.So we think about breaking this double bonds, right?And so if they if they wanted you to give some some reaction conditions here, you can go ahead and, and draw what you would need, right?

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And so if we had a base like sodium carbonate, we're gonna form benzaldehyde and acid aldehyde.

A cinnamaldehyde is the molecule that gives cinnamon its smell, and benzaldehyde smells like almonds, and so this is a pretty cool experiment to do.

We know the carbon next to our carbonyl is our alpha carbon.

And we know the carbon next to that is the beta carbon.

So we're gonna add two hydrogens to our alpha carbon, and that would give us the ketone that we would need.

Right, for our beta carbon, we know there's already a hydrogen attached right here, and so we're going to add an oxygen to this beta carbon on the left, so this is our way of thinking about it.

So we're gonna break that double bond, so on the left, all right, we're gonna have our benzine ring. And then we're gonna have a hydrogen attached to this carbon, attached to our alpha carbon.

And remember, we're gonna add two hydrogens to our alpha carbon.

All right and then if I add an oxygen to that carbon, that would be this oxygen right here. Adding water, right, breaking your double bond and adding an oxygen and two hydrogens will, is one way of thinking about forming your product here. You can think about losing water from this portion and sticking these two fragments together to give you your aldol condensation product.

So once again, this way of thinking can be can be very useful if you're trying to retro synthesize something, so if you're thinking in reverse.

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